Analysis of Mechanical and Tribological Properties of Polyamide and Polyamide-Based Composites Used in Transport
https://doi.org/10.30932/1992-3252-2024-22-5-4
Abstract
Currently, parts made of rubber and polymers are widely used in vehicles. Analysis of domestic and foreign literature has shown that the interaction of steel parts, rubber and polymers at high contact pressures, at which seizure in friction pairs and the effects of free and fixed abrasive on polymer materials and rubber occur, have not been sufficiently studied. Besides, for serially produced polyamides and their composites, the issues of the influence of pressure and sliding speed on friction torque in friction pairs with steel surfaces remain poorly studied.
The paper presents the results of determining the tribological behaviours of PA6 polyamides, oil-filled polyamides with molybdenum disulfide (PA6+MoS2 ), PA6 polyamides filled with graphite (PA6+Gr) during friction on 40X steel with different surface roughness, free and fixed abrasive grain in comparison with the reference material, rubber, nitrile butadiene rubber (NBR).
Tribological tests were performed according to the following schemes: «wide side of a flat sample (polyamide, composite, NBR) – end face of the annular surface of the counter-sample bushing (40X steel) and «annular surface of a rubber disk – wide side of a flat sample (polyamide, composite, NBR)» with quartz sand fed into the friction zone. The objective of the study was to determine the dependence of friction torque on the pressure and sliding speed, the seizure pressure on the sliding speed, the loss of mass of samples during friction on free and fixed abrasive grain of serially manufactured polyamide PA6, and oil-filled polyamides with molybdenum disulfide (PA6+MoS2 ), PA6 polyamides filled with graphite (PA6+Gr) in comparison with the reference material, rubber, NBR. The experimental results can be useful in developing new products and for replacing rubber gaskets, bronze bushings, seals, corrugations and other parts in transport and rolling stock.
About the Authors
V. P. BiryukovRussian Federation
Biryukov, Vladimir P., Ph.D. (Eng), Associate Professor, Leading Researcher of Mechanical Engineering; External Part-Time Worker at the Department of Transport Engineering Technology and Rolling Stock Repair
Moscow
A. A. Yakubovsky
Russian Federation
Yakubovsky, Anton A., Junior Researcher of Mechanical Engineering; Ph.D. Student at the Department of Mechanical Engineering
Moscow
References
1. Horst, J. J., Salienko, N. V., Spoormaker, J. L. Fibermatrix debonding stress analysis for short fiber-reinforced materials with matrix plasticity, finite element modelling and experimental verification. Composites Part A: Applied Science and Manufacturing, 1998, Vol. 29, Iss. 5–6, pp. 525–531. DOI: doi.org/10.1016/S1359-835X(97)00125-5.
2. Cartledge, H. C. Y., Baillie, C. A. Effects of crystallinity, transcrystallinity and crystal phases of GF/PA on friction and ear mechanisms. Journal of Materials Science, 2002, Vol. 37, Iss.14, pp. 3005–22. DOI: doi.org/10.1023/A:1016081317081.
3. Voyer, J., Klien, S., Velkavrh, I. Static and Dynamic Friction of Pure and Friction-Modified PA6 Polymers in Contact with Steel Surfaces: Influence of Surface Roughness and Environmental Conditions. Lubricants, 2019, Vol. 7 (2), pp. 17–31. DOI: doi.org/10.3390/lubricants7020017.
4. Jing Chen, Jiaming Zhu, Yiyue Luo. Achieving enhanced interfacial adhesion and highly oriented structure in PA6/Graphite composites for excellent tribological performance. Composites Science and Technology, 2022, Vo l . 2 2 9 , 1 0 9 7 1 9 . D O I : doi.org/10.1016/j.compscitech.2022.109719.
5. Tianxi Liu, In Yee Phang, Lu Shen, Shue Yin Chow, Wei-De Zhang. Morphology and mechanical properties of multiwalled carbon nanotubes reinforced nylon‑6 composites. Macromolecules, 2004, Vol. 37, Iss. 19, pp. 7214–7222. [Electronic resource]: https://citeseerx.ist.psu.edu/document?repid=rep1&type=pdf&doi=bfe74422fdd68264c3632eecfc26a922a1b7183e. Last accessed 23.08.2024.
6. Tkachenko, E. V. Development of reinforced composites based on polyamide 6 and phenylone C‑1. Ph.D. (Eng) thesis [Razrabotka armirovannykh kompozitov na osnove poliamida 6 i fenilona C‑1. Diss… kand. tekh. nauk]. Sevastopol, SSU publ., 2018, 173 p. [Electronic resource]: https://rguk.ru/upload/iblock/000‑aspirantura/defence-archive/TkachenkoEV/диссертация%20%20Ткаченко%20(3).pdf. Last accessed 22.07.2024.
7. Qiaolie Zheng, Bin Wang, Xiping Li. Microstructural, Mechanical, and Tribological Performances of Composites Prepared via Melt Compounding of Polyamide 6, Basalt Fibers, and Styrene–Ethylene–Butylene–Styrene Copolymer. MDPI Materials, 2023, Vol. 16, pp. 3237. DOI: doi.org/10.3390/ma16083237.
8. Hyung Jin Mun, Jae Ik Kim, Ki Dong Nam. Functionalized hexagonal shaped potassium titanate/PA66 composite for improved wear resistance. Polymer Bulletin, Vol. 78, 2020, pp. 3959–3971. DOI: doi.org/10.1007/s00289020-03307-z.
9. Mengbo Qian, Pingan Song, Zhe Qin. Mechanically robust and abrasion-resistant polymer nanocomposites for potential applications as advanced clearance joints. Composites Part A: Applied Science and Manufacturing, 2019, Vol. 126, p. 105607. DOI: doi.org/10.1016/j.compositesa.2019.105607.
10. Kalani, A., Vadher, J. A., Jani, R. Investigation of thermal and wear behaviour of 3D printed PA‑12 nylon polymer spur gears. El-Cezerî Journal of Science and Engineering, 2022, Vol. 9, Iss. 3, pp. 1121–1135. DOI: doi.org/10.31202/ecjse.1085328.
11. Unal, H., Yetgin, S. H., Kose, S. Tribological performance of polyamide 6/wax blend for rolling bearing, bushing and gear applications. The International Journal of Chemistry and Technology, 2023, Vol. 7, pp. 75–81. DOI: doi.org/10.32571/ijct.1292871.
12. Abdullah, S., Hassan, S. S., Al khazraji, A. N. Investigation of Wear Behavior for Novel Polyamide 66 Composites Under Dry Sliding Conditions. International Journal of Nanoelectronics and Materials, 2020, Vol. 13, Iss. 1, pp. 9–18. [Electronic resource]: https://ijneam.unimap.edu.my/images/PDF/IJNEAM%20JAN%202020%20Vol%2013/Vol_13_No_1_2020_2_9–18.pdf. Last accessed 22.07.2024.
13. Phani, K. S., Suman, K. N. S., Ramanjaneyulu, S. Application of a Novel Decision-Making Algorithm in Development of a Nylon Hybrid Composite for Manufacture of Plastic Gears. Journal of The Institution of Engineers (India): Series D, 2023. DOI: doi.org/10.1007/s40033-02300506-6.
14. Neis, P. D., Ferreira, N. F., Poletto, J. C., Sukumaran, J., Ando, M., Zhang Y. Tribological behavior of polyamide‑6 plastics and their potential use in industrial applications. Elsevier, Wear, 2017, Vol. 376–377, pp. 1391–1398. DOI: doi.org/10.1016/j.wear.2017.01.090.
15. Serbinovskiy, M., Popova, O., Finochenko, T., Serbinovskaya, A. Polyamide self-lubricating composites filled with thermolysis products of lignin: composition, structure, properties. Journal of Physics: Conference Series, 2021, Vol. 2131, pp. 042020. DOI: doi.org/10.1088/17426596/2131/4/042020.
16. Ardila, M. A. N., Costa, H. L., de Mello, J. D. B. Influence of the ball material on friction and wear in microabrasion tests. Wear, 2020, Vol. 450–451, pp. 203266. DOI: doi.org/10.1016/j.wear.2020.203266.
17. Józwik, J., Assessment of Selected Operating Characteristics of Polymer Composites with Non-Ferrous Materials Used in Friction Pairs. Manufacturing Technology, 2019. Vol. 19, Iss. 4, pp. 596–603. DOI: doi.org/10.21062/ujep/340.2019/a/1213-2489/MT/19/4/596.
18. Xin Li, Haiyan Li, Zhike Li, Jing Ji, Sijia Chen, Mingjun Zhang, Beiyao Zha. Preparation of double-walled polysulfone/graphene oxide microcapsules with high thermal stability and their application in self-lubricating polyamide. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2022, Vol. 635, pp. 128111. DOI: doi.org/10.1016/j.colsurfa.2021.128111.
19. Sarankó, A., Kalácska, G., Keresztes, R., Comparison of S 235 steel and DLC coated steel using Pin-on-disc method in dry sliding conditions against PA 6 countersurface. IOP Conference Series: Materials Science and Engineering, 2020, Vol. 749, 012024. DOI: doi.org/10.1088/1757899X/749/1/012024.
20. Biryukov, V. P., Goryunov, Ya. A., Dvoeglazov, A. A., Yakubovsky, A. A. Influence of the polymer material composition on abrasive wear. Journal of advanced research in technical science, 2023, Iss. 34, pp. 13–16. DOI: doi.org/10.26160/2474-5901-2023-34-13-16.
Review
For citations:
Biryukov V.P., Yakubovsky A.A. Analysis of Mechanical and Tribological Properties of Polyamide and Polyamide-Based Composites Used in Transport. World of Transport and Transportation. 2024;22(5):26-33. https://doi.org/10.30932/1992-3252-2024-22-5-4
JATS XML






















